Autor: |
Huang C; Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, United States., Chattopadhyay B, Gevorgyan V |
Jazyk: |
angličtina |
Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2011 Aug 17; Vol. 133 (32), pp. 12406-9. Date of Electronic Publication: 2011 Jul 21. |
DOI: |
10.1021/ja204924j |
Abstrakt: |
A silanol-directed, Pd(II)-catalyzed C-H alkenylation of phenols is reported. This work features silanol, as a novel traceless directing group, and a directed o-C-H alkenylation of phenols. This new method allows for efficient synthesis of diverse alkenylated phenols, including an estrone derivative. |
Databáze: |
MEDLINE |
Externí odkaz: |
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