| Autor: |
Sokolov MN; Nikolaev Institute of Inorganic Chemistry SB RAS, 630090, Lavrentieva st. 3, Novosibirsk, Russia. caesar@niic.nsc.ru, Adonin SA, Mainichev DA, Vicent C, Zakharchuk NF, Danilenko AM, Fedin VP |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Jul 21; Vol. 47 (27), pp. 7833-5. Date of Electronic Publication: 2011 Jun 07. |
| DOI: |
10.1039/c1cc10912j |
| Abstrakt: |
The first Keggin-type heteropolyanion, [PW(11)O(39)Ir(H(2)O)](4-) (1), was synthesized by hydrothermal reaction from two different polytungstate precursors and [IrF(6)](2-). It was isolated as (Bu(4)N)(4)[PW(11)O(39)Ir(H(2)O)] (1a), which was completely characterized by multinuclear (31)P and (183)W NMR, ESI-mass spectrometry and cyclic voltammetry. A rapid screening methodology to ascertain the intrinsic substitutional lability at the Ir site is also presented, based on ESI-MS. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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