| Autor: |
Hindson CM; Deakin University, School of Life and Environmental Sciences, Waurn Ponds 3217, Victoria, Australia., Francis PS, Hanson GR, Barnett NW |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Jul 21; Vol. 47 (27), pp. 7806-8. Date of Electronic Publication: 2011 Jun 01. |
| DOI: |
10.1039/c1cc11434d |
| Abstrakt: |
A chemically initiated adaptation of the classic [Ru(bipy)(3)](2+)/oxalate electrochemiluminescence coreactant system has revealed the elusive radical intermediates of the light-producing pathway. Oxalyl (HC(2)O(4)˙) and hydroxyformyl (HCO(2)˙) radicals have been captured on a quartz surface and characterised using EPR spectroscopy. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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