Bis[N'-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-κO,N',O']manganese(II) N,N-dimethyl-formide monosolvate monohydrate.

Autor: Abdul Halim SN; Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia., Ali HM, Ng SW
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Oct 23; Vol. 66 (Pt 11), pp. m1439. Date of Electronic Publication: 2010 Oct 23.
DOI: 10.1107/S1600536810039516
Abstrakt: In the title compound, [Mn(C(13)H(8)N(3)O(3))(2)]·C(3)H(7)NO·H(2)O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octa-hedral geometry. The N-H groups, the carbonyl group of the DMF mol-ecule and the uncoord-inated water mol-ecule engage in N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, generating a hydrogen-bonded ribbon that propagates along [110].
Databáze: MEDLINE