Autor: |
Abdul Halim SN; Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia., Ali HM, Ng SW |
Jazyk: |
angličtina |
Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Oct 23; Vol. 66 (Pt 11), pp. m1438. Date of Electronic Publication: 2010 Oct 23. |
DOI: |
10.1107/S1600536810039504 |
Abstrakt: |
The metal atom of the title compound, [Zn(C(13)H(8)N(3)O(2)S)(2)]·C(3)H(7)NO·H(2)O, is O,N,O'-chelated by two deprotonated Schiff bases and it exists in a distorted octa-hedral geometry. The N-H groups of the ligands, the carbonyl group of the DMF mol-ecule and uncoordinated water mol-ecule engage in N-H⋯O and O-H⋯O inter-actions, generating a hydrogen-bonded ribbon that propagates along [110]. One thienyl ring is disordered over two positions in a 1:1 ratio. |
Databáze: |
MEDLINE |
Externí odkaz: |
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