Autor: |
Di LL; Basic College Science, Laboratory of Pharmaceutical Chemistry, China Pharmaceutical University, Nanjing, People's Republic of China., Wang Y, Lin GW, Lu T |
Jazyk: |
angličtina |
Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 May 08; Vol. 66 (Pt 6), pp. m610-1. Date of Electronic Publication: 2010 May 08. |
DOI: |
10.1107/S1600536810015631 |
Abstrakt: |
In the title compound, [Zn(C(8)H(5)N(2)O(2))(2)(H(2)O)], the Zn(II) ion is coordinated in each case by a carboxyl-ate O atom and an imidazole N atom from two different benzimidazole-2-carboxyl-ate (BIC) ligands and one water O atom in a trigonal-bipyramidal geometry. In the complex mol-ecule, the two benzimidazole planes are twisted, making a dihedral angle of 55.93 (11)°. The three-dimensional framework is organized by inter-molecular N-H⋯O hydrogen bonding and O-H⋯O inter-actions and π-π inter-actions between adjacent benzimidazole rings [centroid-centroid distance = 3.586 (3) Å]. |
Databáze: |
MEDLINE |
Externí odkaz: |
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