Autor: |
Zebiri I, Anak B, Djebli Y, Boufas S, Bencharif L |
Jazyk: |
angličtina |
Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2009 Aug 12; Vol. 65 (Pt 9), pp. m1063-4. Date of Electronic Publication: 2009 Aug 12. |
DOI: |
10.1107/S1600536809031092 |
Abstrakt: |
The asymmetric unit of the title compound, (C(6)H(4)S(4))(8)[Mo(6)O(19)](2)·CH(3)CN, contains two halves of two centrosymmetric [Mo(6)O(19)](2-) hexa-molybdate anions, which are each built up from six distorted MoO(6) octa-hedra sharing common edges and one common vertex at the central O atom, six tetra-thia-fulvalene cations (three of which are located on mirror planes) to balance the charge and a half of an acetonitrile solvent mol-ecule, likewise located on a mirror plane. The two central hexa-molybdate O atoms occupy special positions 2a and 2d, respectively. The cations and anions are inter-linked through C-H⋯O contacts. |
Databáze: |
MEDLINE |
Externí odkaz: |
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