Development of a new stir bar sorptive extraction coating and its application for the determination of six pesticides in sugarcane juice.

Autor: Barletta JY; Institute of Chemistry of Sao Carlos, University of Sao Paulo, Sao Carlos, Sao Paulo, Brazil., Gomes PC, Dos Santos-Neto AJ, Lancas FM
Jazyk: angličtina
Zdroj: Journal of separation science [J Sep Sci] 2011 Jun; Vol. 34 (11), pp. 1317-25. Date of Electronic Publication: 2011 May 05.
DOI: 10.1002/jssc.201100096
Abstrakt: In this article, a novel polydimethylsiloxane/activated carbon (PDMS-ACB) material is proposed as a new polymeric phase for stir bar sorptive extraction (SBSE). The PDMS-ACB stir bar, assembled using a simple Teflon(®)/glass capillary mold, demonstrated remarkable stability and resistance to organic solvents for more than 150 extractions. The SBSE bar has a diameter of 2.36 mm and a length of 2.2 cm and is prepared to contain 92 μL of polymer coating. This new PDMS-ACB bar was evaluated for its ability to determine the quantity of pesticides in sugarcane juice samples by performing liquid desorption (LD) in 200 μL of ethyl acetate and analyzing the solvent through gas chromatography coupled with mass spectrometry (GC-MS). A fractional factorial design was used to evaluate the main parameters involved in the extraction procedure. Then, a central composite design with a star configuration was used to optimize the significant extraction parameters. The method used demonstrated a limit of quantification (LOQ) of 0.5-40 μg/L, depending on the analyte detected; the amount of recovery varied from 0.18 to 49.50%, and the intraday precision ranged from 0.072 to 8.40%. The method was used in the analysis of real sugarcane juice samples commercially available in local markets.
(Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
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