| Autor: |
Guo ML; School of Environment and Chemical Engineering and Key Laboratory of Hollow Fiber Membrane Materials & Membrane Processes, Tianjin Polytechnic University, Tianjin 300160, People's Republic of China., Liu L, Lu CC |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2010 Dec 04; Vol. 67 (Pt 1), pp. m19-20. Date of Electronic Publication: 2010 Dec 04. |
| DOI: |
10.1107/S1600536810049779 |
| Abstrakt: |
The unit-cell parameters for the title mixed-metal coordination polymer, {[NiSr(C(3)H(2)O(4))(2)(H(2)O)(5)]·2H(2)O}(n), which is isostructural with its Co-containing analogue, were reported previously [Gil de Muro et al. (1999 ▶). Eur. J. Inorg. Chem. pp. 935-943]; the full crystal structure including a description of the hydrogen bonding is reported here. The Sr(2+) ion is bonded to five O atoms from three different malonate dianions and four water mol-ecules, displaying a distorted tricapped trigonal-prismatic coordination geometry. Two malonate dianions, two water mol-ecules and one Ni(2+) ion build up a dianionic [Ni(C(3)H(2)O(4))(2)(H(2)O)(2)](2-) unit incorporating a slightly distorted NiO(6) octa-hedron, which coordinates to three nearby Sr(2+) ions. This arrangement creates a metal-organic framework having a 20-membered ring with four Ni and six Sr atoms lying in the bc plane. The coordinated and uncoordinated water mol-ecules are responsible for the formation of two D5 hydrogen-bonded water chains within the 20-membered ring and they are linked into an R4 water cluster via two bifurcated O-H⋯(O,O) links. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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