Direct functionalisation of group 10 N-heterocyclic carbene complexes for diversity enhancement.

Autor: Chardon E; Institute of Physics and Chemistry of Materials of Strasbourg (IPCMS), University of Strasbourg - CNRS UMR7504, 23 rue du Loess, 67034 Strasbourg, France., Puleo GL, Dahm G, Guichard G, Bellemin-Laponnaz S
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 May 28; Vol. 47 (20), pp. 5864-6. Date of Electronic Publication: 2011 Apr 18.
DOI: 10.1039/c1cc11391g
Abstrakt: The synthesis of alkyne-substituted N-heterocyclic carbene complexes of Pd(II) and Pt(II) is reported. Catalyzed 1,3-dipolar cycloaddition with azides has been applied as a modular way of functionalisation of group 10 transition metal NHC complexes to generate potentially new metallodrugs.
(© The Royal Society of Chemistry 2011)
Databáze: MEDLINE