Allene functionalization via bicyclic methylene aziridines.
| Autor: | Boralsky LA; Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA., Marston D, Grigg RD, Hershberger JC, Schomaker JM |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | Organic letters [Org Lett] 2011 Apr 15; Vol. 13 (8), pp. 1924-7. Date of Electronic Publication: 2011 Mar 25. |
| DOI: | 10.1021/ol2002418 |
| Abstrakt: | The oxidative functionalization of olefins is a common method for the formation of vicinal carbon-heteroatom bonds. However, oxidative methods to transform allenes into synthetic motifs containing three contiguous carbon-heteroatom bonds are much less developed. This paper describes the use of bicyclic methylene aziridines (MAs), prepared via intramolecular allene aziridination, as scaffolds for functionalization of all three allene carbons. (© 2011 American Chemical Society) |
| Databáze: | MEDLINE |
| Externí odkaz: |
|