Surface functionalization of metal-organic polyhedron for homogeneous cyclopropanation catalysis.
| Autor: | Lu W; Department of Chemistry, Texas A&M University, College Station, TX 77843, USA., Yuan D, Yakovenko A, Zhou HC |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 May 07; Vol. 47 (17), pp. 4968-70. Date of Electronic Publication: 2011 Mar 22. |
| DOI: | 10.1039/c1cc00030f |
| Abstrakt: | A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst. (© The Royal Society of Chemistry 2011) |
| Databáze: | MEDLINE |
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