Autor: |
Jenkinson SF, Booth KV, Best D, Fleet GW, Watkin DJ |
Jazyk: |
angličtina |
Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2008 Sep 27; Vol. 64 (Pt 10), pp. o2011-2. Date of Electronic Publication: 2008 Sep 27. |
DOI: |
10.1107/S160053680803064X |
Abstrakt: |
The relative configuration of tert-butyl 2-de-oxy-4,5-O-iso-propyl-idene-d-gluconate, C(13)H(24)O(6), an inter-mediate in the synthesis of 2-de-oxy sugars, was determined by X-ray crystallography, and the crystal structure consists of chains of O-H⋯O hydrogen-bonded mol-ecules running parallel to the a axis. There are two mol-ecules in the asymmetric unit. The absolute configuration was inferred from the use of d-erythrono-lactone as the starting material. |
Databáze: |
MEDLINE |
Externí odkaz: |
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