Autor: |
Antczak MI; Department of Biochemistry, The University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, USA., Cai F, Ready JM |
Jazyk: |
angličtina |
Zdroj: |
Organic letters [Org Lett] 2011 Jan 21; Vol. 13 (2), pp. 184-7. Date of Electronic Publication: 2010 Dec 13. |
DOI: |
10.1021/ol102567h |
Abstrakt: |
Vinyl, aryl, and alkynyl organometallics add to ketones containing a stereogenic sulfoxide. Tertiary alcohols are generated in diastereomerically and enantiomerically pure form. Reductive lithiation converts the sulfoxide into a variety of useful functional groups. |
Databáze: |
MEDLINE |
Externí odkaz: |
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