Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal-organic framework.

Autor: Sapchenko SA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation., Samsonenko DG, Dybtsev DN, Melgunov MS, Fedin VP
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2011 Mar 14; Vol. 40 (10), pp. 2196-203. Date of Electronic Publication: 2010 Nov 22.
DOI: 10.1039/c0dt00999g
Abstrakt: Zn(II)-containing metal-organic framework (MOF) [Zn(4)(dmf)(ur)(2)(ndc)(4)] (ndc(2-) = 2,6-naphtalenedicarboxylate, ur = urotropin, dmf = N,N'-dimethylformamide) was synthesized and characterized by X-ray crystallography and gas sorption analysis. Host MOF retains its crystallinity after guest removal and exchange. Single-crystal to single-crystal formation of different host-guest systems with benzene and ferrocene was investigated. Interesting guest-depended luminescence properties of the porous host framework were observed.
Databáze: MEDLINE