A new oxomolybdate component extracted from the "virtual dynamic library" yielding the macrocyclic anion [(Mo(VI)(8)O(28))(4)(Mo(V)(2)O(2)S(2))(4)](24-).

Autor: Korenev VS; Institut Lavoisier de Versailles, Université de Versailles Saint Quentin, UMR 8180, 45 avenue des Etats Unis, 78035 Versailles, France., Boulay AG, Dolbecq A, Sokolov MN, Hijazi A, Floquet S, Fedin VP, Cadot E
Jazyk: angličtina
Zdroj: Inorganic chemistry [Inorg Chem] 2010 Nov 01; Vol. 49 (21), pp. 9740-2.
DOI: 10.1021/ic101545w
Abstrakt: A rare isomer of the {Mo(8)O(28)}(8-) anion has been trapped from an acidified aqueous solution of molybdate by using the {Mo(2)O(2)S(2)}(2+) oxothio cation as the linker and isolated as a part of a unique macrocyclic anion, which consists of four isopolyoxomolybdate fragments {Mo(8)O(28)} bridged by four {Mo(2)O(2)S(2)} units.
Databáze: MEDLINE