| Autor: |
Sadasivam DV; Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA., Teprovich JA Jr, Procter DJ, Flowers RA 2nd |
| Jazyk: |
angličtina |
| Zdroj: |
Organic letters [Org Lett] 2010 Sep 17; Vol. 12 (18), pp. 4140-3. |
| DOI: |
10.1021/ol101722c |
| Abstrakt: |
Mechanistic studies show the importance of iodide displacement by additives that accelerate reactions of samarium diiodide. The key feature important for acceleration of reaction rate is the use of proton donors and other additives that have a high enough affinity for Sm(II) to displace iodide yet do not saturate the coordination sphere inhibiting substrate reduction. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
