Selective formation of propylene by hexane cracking over MCM-68 zeolite catalyst.

Autor: Inagaki S; Division of Materials Science and Chemical Engineering, Yokohama National University, 79-5, Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan., Takechi K, Kubota Y
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Apr 21; Vol. 46 (15), pp. 2662-4.
DOI: 10.1039/b925408k
Abstrakt: Dealumination of MCM-68 zeolite with MSE topology enhanced the selectivity to propylene (45-50%) and durability to coke formation during hexane cracking, regardless of the reaction temperature, which is attributed to the control of the position and density of acid sites originating from the framework Al atoms.
Databáze: MEDLINE