| Autor: |
Mendoza-Espinosa D; UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, California 92521-0403, USA., Donnadieu B, Bertrand G |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2010 Jun 02; Vol. 132 (21), pp. 7264-5. |
| DOI: |
10.1021/ja102639a |
| Abstrakt: |
Using the nucleophilicity of NHCs and aNHCs, as well as the leaving group ability of the former, the carbon-carbon double bond of imidazol-2-ylidenes can be readily mono- and difunctionalized. These results provide also a new light on the formation of abnormal carbene adducts from classical unsaturated NHCs. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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