| Autor: |
Sherwood RK; Department of Chemistry, University of British Columbia Okanagan, 3333 University Way, Kelowna BC, Canada., Kent CL, Patrick BO, McNeil WS |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2010 Apr 14; Vol. 46 (14), pp. 2456-8. Date of Electronic Publication: 2010 Feb 23. |
| DOI: |
10.1039/b922030e |
| Abstrakt: |
Cobalt-mediated radical polymerisation of methyl acrylate is effected at moderate temperature by both a square planar bis(beta-ketoaminato)cobalt(II) complex in the presence of V-70 diazo radical initiator, and by a well-defined cobalt(III) alkyl derivative in the absence of a diazo complex. Polymerisation rates suggest that both reversible termination and degenerative transfer mechanisms are operative. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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