| Autor: |
Roy LN, Roy RN, Lenoue SR, Denton CE, Fuge MS, Dunseth CD, Roy CN, Hayden SM, Wollen JT, Sreepada K |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of solution chemistry [J Solution Chem] 2009 Apr 01; Vol. 38 (4), pp. 459-469. |
| DOI: |
10.1007/s10953-009-9379-2 |
| Abstrakt: |
The values of the second dissociation constant, pK(2), and related thermodynamic quantities of 3-[N,N-bis (2-hydroxyethyl)amino]-2-hydroxypropanesulfonic acid (DIPSO) have already been reported over the temperature range 5 to 55 degrees C including 37 degrees C. This paper reports the pH values of four NaCl-free buffer solutions and four buffer composition containing NaCl salt at I = 0.16 mol.kg(-1). Conventional pa(H) values are reported for all eight buffer solutions. The operational pH values have been calculated for four buffer solutions recommended as pH standards, at 25 and 37 degrees C after correcting the liquid junction potentials with the flowing junction cell. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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