Ten-vertex {closo-2,1,10-FeC2B7} clusters with intramolecular imidate linkages: anchors for supramolecular construction.

Autor: Franken A; Department of Chemistry & Biochemistry, Baylor University, Waco, TX 76798-7348, USA., McGrath TD, Stone FG
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2009 Sep 28 (36), pp. 7353-5. Date of Electronic Publication: 2009 Jul 23.
DOI: 10.1039/b910146b
Abstrakt: Intramolecular hydroxyl attack upon iron-coordinated nitriles in a {closo-2,1,10-FeC2B7} system forms imidates that allow construction of a tetra-cluster {FeC2B7}-{C2Co2}-{C2Co2}-{FeC2B7} molecule.
Databáze: MEDLINE