| Autor: |
Spokoyny AM; Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA., Reuter MG, Stern CL, Ratner MA, Seideman T, Mirkin CA |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2009 Jul 15; Vol. 131 (27), pp. 9482-3. |
| DOI: |
10.1021/ja902526k |
| Abstrakt: |
We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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