| Autor: |
Bonyhady SJ; School of Chemistry, Monash University, PO Box 23, VIC, 3800, Australia., Green SP, Jones C, Nembenna S, Stasch A |
| Jazyk: |
angličtina |
| Zdroj: |
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2009; Vol. 48 (16), pp. 2973-7. |
| DOI: |
10.1002/anie.200900331 |
| Abstrakt: |
The odd couple: A dimeric magnesium(I) complex acts as a facile and selective two-center/two-electron reductant towards a series of unsaturated substrates (see scheme; Ar = 2,6-iPr(2)C(6)H(3), Ad = 1-adamantyl). The novel reduced or reductively coupled products obtained from these reductions suggest that magnesium(I) compounds may find wide use in organic and organometallic syntheses. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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