| Autor: |
Fernández TL; Departamento de Química Inorgânica, Instituto de Química, Universidade Federal do Rio de Janeiro, 21945-970 Rio de Janeiro, RJ, Brazil., Souza ET, Visentin LC, Santos JV, Mangrich AS, Faria RB, Antunes OA, Scarpellini M |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of inorganic biochemistry [J Inorg Biochem] 2009 Apr; Vol. 103 (4), pp. 474-9. Date of Electronic Publication: 2009 Feb 13. |
| DOI: |
10.1016/j.jinorgbio.2009.02.001 |
| Abstrakt: |
A vanadyl complex with the ligand (bis(1-methylimidazol-2-yl)methyl)(2-(pyridyl-2-yl)ethyl)amine was synthesized and fully characterized by X-ray crystallography, elemental analyses, cyclic voltammetry and infrared, electronic and electron paramagnetic resonance spectroscopies. This compound was designed under the so called hybrid concept. It shows to be able to promiscuously use hydrogen peroxide to oxidize bromide and to catalyze the oxidation of benzene and cyclohexane with very good selectivities. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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