Efficient asymmetric transfer hydrogenation of ketones catalyzed by an iron complex containing a P-N-N-P tetradentate ligand formed by template synthesis.

Autor: Mikhailine A; Davenport Laboratory, Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6, Canada., Lough AJ, Morris RH
Jazyk: angličtina
Zdroj: Journal of the American Chemical Society [J Am Chem Soc] 2009 Feb 04; Vol. 131 (4), pp. 1394-5.
DOI: 10.1021/ja809493h
Abstrakt: A distorted iron complex formed by template synthesis is the basis of a very efficient and economical catalyst system for the asymmetric transfer hydrogenation of ketones for the production of valuable enantioenriched alcohols.
Databáze: MEDLINE