Snowman-like silver alkynyl cluster consolidated by templating chloride and peripheral trifluoroacetates.

Autor: Bian SD; Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen, 361005, People's Republic of China., Wang QM
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2008 Nov 21 (43), pp. 5586-8. Date of Electronic Publication: 2008 Sep 25.
DOI: 10.1039/b812451e
Abstrakt: A novel nonadecanuclear silver double cage was isolated, in which a square antiprism and a pentacapped pentagonal prism templated by a chloride ion share a tetragonal face to form a snowman-like cluster that is held together by bridging alkynyl groups and trifluoroacetates.
Databáze: MEDLINE