| Autor: |
Detter LD; Purdue University, Chemistry Department, West Lafayette, IN 47907, U.S.A., Pachuta SJ, Cooks RG, Walton RA |
| Jazyk: |
angličtina |
| Zdroj: |
Talanta [Talanta] 1986 Nov; Vol. 33 (11), pp. 917-8. |
| DOI: |
10.1016/0039-9140(86)80224-7 |
| Abstrakt: |
Vacuum-promoted ligand loss has been detected for the complexes [Ag(CNMe)(4)]PF(6) (Me = methyl), [Ag(CN-t-Bu)(4)]ClO(4) (t-Bu = tert-butyl) and [Ag(CNCy)(4)]ClO(4) (Cy = cyclohexyl). The analogous Cu(I) isocyanide complexes are stable under the same conditions. These conclusions are based on infrared spectroscopy, secondary-ion mass-spectrometry (SIMS) and weight-loss measurements. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
