| Autor: |
Balyatinskaya LN; D. I. Mendeleev Institute of Chemical Technology, Moscow, USSR., Kreshkov AP |
| Jazyk: |
angličtina |
| Zdroj: |
Talanta [Talanta] 1982 Feb; Vol. 29 (2), pp. 153-5. |
| DOI: |
10.1016/0039-9140(82)80041-6 |
| Abstrakt: |
The methods for thermodynamic calculations of the equilibria in solutions of mercury salts and complexes are presented. The calculations of equilibrium constants in non-aqueous solvents are based on the transfer activity coefficients of mercury ions from water to the non-aqueous solvent. The dismutation and precipitation reaction constants are calculated, and the redox potentials of mercury systems are measured. Examples of analytical use of the thermodynamic functions of mercury salt solvation are given in the text. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
