Spectrophotometric determination of tetrafluoroborate with ferroin.

Autor: Archer VS; Department of Chemistry, University of Wyoming, Laramie, Wyoming 82070, U.S.A., Doolittle FG, Young LM
Jazyk: angličtina
Zdroj: Talanta [Talanta] 1968 Aug; Vol. 15 (8), pp. 864-6.
DOI: 10.1016/0039-9140(68)80183-3
Abstrakt: A spectrophotometric method for determination of the tetrafluoroborate anion with ferroin is described. The ferroin tetrafluoroborate is selectively extracted in the presence of excess of ferroin into n-butyronitrile, and the absorbance of the organic extract is measured at 520 mmicro. Beer's law is followed over a wide range of tetrafluoroborate concentrations when a single extraction procedure is used. Exhaustive extractions indicate that 74 % of the tetrafluoroborate is removed in a single extraction.
Databáze: MEDLINE