| Autor: |
Joo CG; Francis Bitter Magnet Laboratory and Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA., Casey A, Turner CJ, Griffin RG |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2009 Jan 14; Vol. 131 (1), pp. 12-3. |
| DOI: |
10.1021/ja805521y |
| Abstrakt: |
Dynamic nuclear polarization is combined with temperature-jump methods to develop a new 2D 13C-13C NMR experiment that yields a factor of 100-170 increase in sensitivity. The polaization step is performed at 100 K, and the sample is subsequently melted with a 10.6 microm laser pulse to yield a sample with highly polarized 13C spins. 13C detected 2D 13C-13C spectroscopy is performed in the usual manner. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
