| Autor: |
Merican Z; Chemistry, School of Science and Technology, University of New England, Armidale, NSW 2351, Australia., Johnstone KD, Gunter MJ |
| Jazyk: |
angličtina |
| Zdroj: |
Organic & biomolecular chemistry [Org Biomol Chem] 2008 Jul 21; Vol. 6 (14), pp. 2534-43. Date of Electronic Publication: 2008 May 16. |
| DOI: |
10.1039/b804267e |
| Abstrakt: |
pi-pi Stacking interactions between electron deficient naphthalenediimides (NDI) and electron-rich porphyrins (POR) leading to charge transfer are shown to be prevalent in linked NDI-POR and POR-NDI-POR structures. For flexibly-linked systems, intramolecular interactions lead to S-shaped foldamers in solution, whereas intermolecular association is predominant in more rigid systems. The foldamer structures can be interrupted by competing aromatic solvents, by six-coordination of metallated porphyrin derivatives, by protonation of the free base porphyrin in non-metallated structures, and in facially sterically hindered porphyrins. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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