| Autor: |
Dubinina GG; Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, Hawaii 96822, USA., Furutachi H, Vicic DA |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2008 Jul 09; Vol. 130 (27), pp. 8600-1. Date of Electronic Publication: 2008 Jun 11. |
| DOI: |
10.1021/ja802946s |
| Abstrakt: |
The first examples of isolable and structurally characterized Cu(I)-CF3 complexes are reported. N-Heterocyclic carbene (NHC)-supported copper tert-butoxide complexes reacted with Me3Si-CF3 to afford new (NHC)Cu-CF3 complexes whose structures were dependent on whether or not the C4-C5 positions of the five-membered NHC rings were saturated. In situ generated (SIiPr)Cu-CF3 cleanly transferred its trifluoromethyl group to a number of organic halides under mild conditions. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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