An atom-efficient and practical synthesis of new pyridinium ionic liquids and application in Morita-Baylis-Hillman reaction.

Autor: Zhao S; Department of Chemistry, Xinzhou Teachers University, Xinzhou 034000, China. sanhuzhao@yahoo.cn, Zhao E, Shen P, Zhao M, Sun J
Jazyk: angličtina
Zdroj: Ultrasonics sonochemistry [Ultrason Sonochem] 2008 Sep; Vol. 15 (6), pp. 955-9. Date of Electronic Publication: 2008 Mar 04.
DOI: 10.1016/j.ultsonch.2008.02.011
Abstrakt: New ionic liquids containing (3-chloro-2-hydroxypropyl)-functionalized pyridinium cations have been synthesized by the ultrasound-assisted, atom-efficient, room temperature reaction of pyridine with acid and 3-chloro-propylene oxide, the acid providing the anionic component of the resultant ionic liquids, and under the ultrasound, a clear yield increase results and a dramatic reduction of the reaction time accompanied by an improved quality of the products occurs. Furthermore, the application of new ionic liquids were tested as solvents in Morita-Baylis-Hillman reaction, in some cases, good results were obtained.
Databáze: MEDLINE