| Autor: |
Cheong PH; Department of Chemistry, University of California, Berkeley, California 94720, USA., Morganelli P, Luzung MR, Houk KN, Toste FD |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2008 Apr 02; Vol. 130 (13), pp. 4517-26. Date of Electronic Publication: 2008 Mar 08. |
| DOI: |
10.1021/ja711058f |
| Abstrakt: |
Tris(triphenylphosphinegold) oxonium tetrafluoroborate, [(Ph3PAu)3O]BF4, catalyzes the rearrangement of 1,5-allenynes to produce cross-conjugated trienes. Experimental and computational evidence shows that the ene reaction proceeds through a unique nucleophilic addition of an allene double bond to a cationic phosphinegold(I)-complexed phosphinegold(I) acetylide, followed by a 1,5-hydrogen shift. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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