| Autor: |
Pakoulev AV; Department of Chemistry, University of Wisconsin, Madison, WI 53706, USA., Rickard MA, Mathew NA, Kornau KM, Wright JC |
| Jazyk: |
angličtina |
| Zdroj: |
The journal of physical chemistry. A [J Phys Chem A] 2007 Aug 02; Vol. 111 (30), pp. 6999-7005. Date of Electronic Publication: 2007 Jul 12. |
| DOI: |
10.1021/jp071929+ |
| Abstrakt: |
Coherent multidimensional spectroscopy performed in the mixed frequency/time domain exhibits both temporal and spectral quantum beating when two quantum states are simultaneously excited. The excitation of both quantum states can occur because either the spectral width of the states or the excitation pulse exceeds the frequency separation of the quantum states. The quantum beating appears as a line that broadens and splits into two peaks and then recombines as the time delay between excitation pulses increases. The splitting depends on the spectral width of the excitation pulses. We observe the spectral quantum beating between the two nearly degenerate asymmetric carbonyl stretch modes in a nickel tricarbonyl chelate using the nonrephasing, ground state bleaching coherence pathway in triply vibrationally enhanced four-wave mixing as the time delay between the first two excitation pulses changes. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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