Autor: |
Stork JR; Department of Chemistry, Buffalo State College, 1300 Elmwood Avenue, Buffalo, NY 14222-1095, USA., Brewer JJ, Fukuda T, Fitzgerald JP, Yee GT, Nazarenko AY, Kobayashi N, Durfee WS |
Jazyk: |
angličtina |
Zdroj: |
Inorganic chemistry [Inorg Chem] 2006 Aug 07; Vol. 45 (16), pp. 6148-51. |
DOI: |
10.1021/ic051093u |
Abstrakt: |
cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato]boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations. |
Databáze: |
MEDLINE |
Externí odkaz: |
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