| Autor: |
Kishali NH; Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, 25240 Erzurum, Turkey. nhorasan@atauni.edu.tr, Sahin E, Kara Y |
| Jazyk: |
angličtina |
| Zdroj: |
Organic letters [Org Lett] 2006 Apr 27; Vol. 8 (9), pp. 1791-3. |
| DOI: |
10.1021/ol060272s |
| Abstrakt: |
[reaction: see text] A new and stereospecific synthesis for bis-endoperoxide has been developed starting from tetrahydronaphthalene. Photooxygenation of tetrahydronaphthalene resulted in the formation of hydroperoxy-endoperoxide. The bromination reaction of hydroperoxy-endoperoxide gave bis-endoperoxide, whose exact configuration has been determined by X-ray analysis. The lowest-energy conformer of bis-endoperoxide is the boat-chair form. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
