| Autor: |
Romanenko KV; Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences, Novosibirsk 630090, Russia. kostaromavita@ngs.ru, Py X, d'Espinose de Lacaillerie JB, Lapina OB, Fraissard J |
| Jazyk: |
angličtina |
| Zdroj: |
The journal of physical chemistry. B [J Phys Chem B] 2006 Feb 23; Vol. 110 (7), pp. 3055-60. |
| DOI: |
10.1021/jp055064g |
| Abstrakt: |
(129)Xe NMR has been used to study a series of homologous activated carbons obtained from a KOH-activated pitch-based carbon molecular sieve modified by air oxidation/pyrolysis cycles. A clear correlation between the pore size of microporous carbons and the (129)Xe NMR of adsorbed xenon is proposed for the first time. The virial coefficient delta(Xe)(-)(Xe) arising from binary xenon collisions varied linearly with the micropore size and appeared to be a better probe of the microporosity than the chemical shift extrapolated to zero pressure. This correlation was explained by the fact that the xenon collision frequency increases with increasing micropore size. The chemical shift has been shown to vary very little with temperature (less than 9 ppm) for xenon trapped inside narrow and wide micropores. This is indicative of a smooth xenon-surface interaction potential. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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