| Autor: |
García-Fortanet J; Department of Biochemistry, University of Texas Southwestern Medical Center at Dallas, 5323 Harry Hines Blvd., Dallas, TX 75390-9038, USA., Debergh JR, De Brabander JK |
| Jazyk: |
angličtina |
| Zdroj: |
Organic letters [Org Lett] 2005 Feb 17; Vol. 7 (4), pp. 685-8. |
| DOI: |
10.1021/ol047507p |
| Abstrakt: |
Herein, we propose a modular and general strategy to construct orcinol-type depsides based on the photolysis of functionalized benzodioxinones (I). Notably, resorcinylic esters are obtained without competing isocoumarin (II) formation, exemplified by the first total synthesis of gustastatin in 10 steps from commercially available trihydroxybenzoic acid. [Structure: see text] |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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