| Autor: |
Alvarez CS; Chemistry Department, University of Cambridge, UK., Boss SR, Burley JC, Humphry SM, Layfield RA, Kowenicki RA, McPartlin M, Rawson JM, Wheatley AE, Wood PT, Wright DS |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2004 Nov 07 (21), pp. 3481-7. Date of Electronic Publication: 2004 Sep 21. |
| DOI: |
10.1039/B409135C |
| Abstrakt: |
Manganocene, Cp(2)Mn, has been employed as a precursor in the synthesis of a range of Mn(II) dimers of the type [CpMn(micro-X)](2)[X = 8-NHC(9)H(6)N (1), N(Ph)(C(5)H(4)N)(2), N(4-EtC(6)H(4))(C(5)H(4)N)(3) and C[triple bond]CPh (4)] as well as the bis-adduct [Cp(2)Mn[HN=C(NMe(2))(2)](2)](5). The solid-state structures of 1-5 are reported. Variable-temperature magnetic measurements have been used to assess the extent of Mn(micro-X)Mn communication within the dimers of 1-4 as a function of the bridging ligands (X). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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