A new synthetic route to metal trithiophosphonates: syntheses and structures of [(C6H11)PS3Li2).THF.TMEDA]2 and [(C6H11))PS3Mg.2THF]2.

Autor: Bjernemose JK; Department of Chemistry, University of Bath, Bath BA2 7AY, UK., Davies RP, Jurd AP, Martinelli MG, Raithby PR, White AJ
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2004 Oct 21 (20), pp. 3169-70. Date of Electronic Publication: 2004 Sep 20.
DOI: 10.1039/B412488J
Abstrakt: A new synthesis for trithiophosphonates from primary phosphines, nBuLi (or nBu(2)Mg) and elemental sulfur is presented and its mechanism investigated; the lithium and magnesium salts of cyclohexyltrithiophosphonate have been fully characterised to reveal dimers in the solid state in which all three of the trithiophosphonate sulfurs are involved in metal bonding.
Databáze: MEDLINE