Ring selectivity and migratory aptitude of Cp*Ru+ complexation to acecorannulene.

Autor: Seiders TJ; Department of Chemistry, University of California-San Diego, La Jolla, CA 92093-0358, USA., Baldridge KK, O'Connor JM, Siegel JS
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2004 Apr 21 (8), pp. 950-1. Date of Electronic Publication: 2004 Mar 12.
DOI: 10.1039/b316061k
Abstrakt: Synthesis and spectral characterization of acecorannulene CpRu+ complexes, in combination with ab initio quantum chemical computations, leads to the hypothesis that eta6-metal binding prefers the exo face in the region of least curvature.
Databáze: MEDLINE