| Autor: |
Baptistella LH; Instituto de Química, UNICAMP, CP 6154, 13084-971 Campinas, SP, Brazil. lhbb@iqm.unicamp.br, Cerchiaro G |
| Jazyk: |
angličtina |
| Zdroj: |
Carbohydrate research [Carbohydr Res] 2004 Feb 25; Vol. 339 (3), pp. 665-71. |
| DOI: |
10.1016/j.carres.2003.10.026 |
| Abstrakt: |
A highly stereocontrolled synthesis of a beta-D-ribo-hept-6-ulopyranosuronamide derivative, a useful intermediate for the synthesis of other higher sugars, has been developed using naturally occurring (-)-quinic acid as a chiral starting material. The transformation of carbocycle to carbohydrate, a key step in this sequence, occurred in a one-pot reaction: an ozonolysis carried out under mild conditions. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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