| Autor: |
Marinescu L; Department of Chemistry, Aarhus University, Langelandsgade 140, DK-8000 Aarhus C, Denmark., Thinggaard J, Thomsen IB, Bols M |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 2003 Nov 28; Vol. 68 (24), pp. 9453-5. |
| DOI: |
10.1021/jo035163v |
| Abstrakt: |
Aliphatic and aromatic aldehydes can be converted to acyl azides by treatment with iodine azide at 0-25 degrees C. If the reaction is performed at reflux Curtius rearrangement occurs and carbamoyl azides are obtained in 70-97% yield from the aldehyde. The reaction was shown to have a radical mechanism. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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