Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C-B bond formation with aryl halides.

Autor: Euzenat L; S. E. S. O. UMR-CNRS 6510, Université de Rennes1-Beaulieu, F-35042, Rennes, France., Horhant D, Ribourdouille Y, Duriez C, Alcaraz G, Vaultier M
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2003 Sep 21 (18), pp. 2280-1.
DOI: 10.1039/b306874a
Abstrakt: Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N-BH2 (R1 and R2 = alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N-BHR3 (R3 = aryl).
Databáze: MEDLINE