| Autor: |
Cooper PD; Chemistry, M313, School of Biomedical and Chemical Sciences, The University of Western Australia, 35 Stirling Highway, Crawley, Australia., Kjaergaard HG, Langford VS, McKinley AJ, Quickenden TI, Schofield DP |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2003 May 21; Vol. 125 (20), pp. 6048-9. |
| DOI: |
10.1021/ja034388k |
| Abstrakt: |
We have measured the infrared spectrum of H2O.HO in argon matrices at 11.5 +/- 0.5 K. We have also calculated the vibrational frequencies and intensities of the H2O.HO complex. As a result of these measurements and calculations, we have assigned a previously unassigned absorption band at 3442.1 cm-1 to the OH stretch in the radical complexed to the water molecule. This absorption originates from a complex that is situated in a different site within the argon matrix to those absorptions already assigned to this vibration at 3452.2 and 3428.0 cm-1. We observe a decrease in intensity of the OH radical stretching vibration of the H2O.HO complex upon isotopic substitution of D for H that agrees well with our calculations. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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