Characterization of a Cu(II) complex of sulfadimethoxine.

Autor: Torre MH; Cátedra de Química Inorgánica, Facultad de Química, Universidad de la República, Montevideo, Uruguay., Facchin G, Kremer E, Castellano EE, Piro OE, Baran EJ
Jazyk: angličtina
Zdroj: Journal of inorganic biochemistry [J Inorg Biochem] 2003 Feb 01; Vol. 94 (1-2), pp. 200-4.
DOI: 10.1016/s0162-0134(02)00632-3
Abstrakt: The molecular structure of [Cu(sulfadimet)(2)].SO(CH(3))(2) (sulfadimet=sulfadimethoxine=4-p-aminobenzenesulfonamido-2,6-dimethoxypyrimidine) was determined by single crystal X-ray diffractometry. It crystallizes in the monoclinic space group P2(1)/c with Z=4. The Cu(II) cation is in a distorted CuN(5) square pyramidal coordination, involving four sulfadimethoxine molecules, one of them acting as a bidentate ligand. The infrared spectrum is briefly discussed on the basis of the structural peculiarities of the complex.
Databáze: MEDLINE