Novel gas-phase ion-molecule aromatic nucleophilic substitution in beta-carbolines.

Autor: Lopes NP; Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK CB2 1EW., Fonseca T, Wilkins JP, Staunton J, Gates PJ
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2003 Jan 07 (1), pp. 72-3.
DOI: 10.1039/b210117c
Abstrakt: We report a novel gas-phase ion-molecule aromatic-nucleophilic substitution reaction between beta-carbolines and water vapour, that accounts for the observation of ions with higher masses than the precursor ion in the MS/MS spectra.
Databáze: MEDLINE