| Autor: |
McMorris TC; Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla 92093-0506, USA. tmcmorris@ucsd.edu, Staake MD |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 2002 Nov 01; Vol. 67 (22), pp. 7902-3. |
| DOI: |
10.1021/jo026030x |
| Abstrakt: |
Reduction of (+/-)-5-chloro-5-methyl-2-cyclopentenone with BH(3).THF and catalytic (R)-2-methyl-CBS-oxazaborolidine gave readily separable diastereomers with high ee values. Oxidation of the diastereomers furnished the enantiomers of the chloromethylcyclopentenone. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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